\begin{align}
\begingroup
% sets length between columns five points.
\setlength\arraycolsep{5pt}
\begin{bmatrix}
...
\end{bmatrix}
\endgroup
\end{align}
\begin{align}
\begingroup
% sets length between columns five points.
\setlength\arraycolsep{5pt}
\begin{bmatrix}
...
\end{bmatrix}
\endgroup
\end{align}